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SOLVENT AND PH EFFECT ON THE ABSORPTION AND FLUORESCENCE SPECTRA OF 5-[(2,3-DIHYDROXYBENZALIDENE)-AM > cuba4

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SOLVENT AND PH EFFECT ON THE ABSORPTION AND FLUORESCENCE SPECTRA OF 5-…

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SOLVENT AND PH EFFECT ON THE ABSORPTION AND FLUORESCENCE SPECTRA OF 5-[(2,3-DIHYDROXYBENZALIDENE)-AM
Abstract






SOLVENT AND PH EFFECT ON THE ABSORPTION AND FLUORESCENCE SPECTRA OF 5-[(2,3-DIHYDROXYBENZALIDENE)-AMINO] NAPHTHALENE-2-SULFONIC ACID

SOLVENT AND PH EFFECT ON THE ABSORPTION AND FLUORESCENCE SPECTRA OF 5-[(2,3-DIHYDROXYBENZALIDENE)-AMINO] NAPHTHALENE-2-SULFONIC ACID
SOLVENT AND PH EFFEC-3770_01_.jpg SOLVENT AND PH EFFEC-3770_02_.jpg SOLVENT AND PH EFFEC-3770_03_.jpg SOLVENT AND PH EFFEC-3770_04_.jpg SOLVENT AND PH EFFEC-3770_05_.jpg
To investigate the solvent effect, we measured the absorption spectra using the mixture of DMSO and ethanol. Also, the excitation spectra of DMSO-deionized water. The larger the ratio of DMSO, the greater the absorbance and the intensity. At various pH, the absorption and fluorescence spectra were measured and it was concluded that the results at pH 9.45 was the best. Therefore, the effect of several tripositive cation was conducted at pH 9.45. As anticipated, the spectra were shown to become very different when the metal ions(Al3+, Cr3+, Fe3+) were mixed to the ligand solution (solvent), ethanol: H2O= 4:1). 


SOLVENT AND PH EFFECT ON THE ABSORPTION AND FLUORESCENCE SPECTRA OF 5-[(2,3-DIHYDROXYBENZALIDENE)-AMINO] NAPHTHALENE-2-SULFONIC ACID
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SOLVENT AND PH EFFECT ON THE ABSORPTION AND FLUORESCENCE SPECTRA OF 5-[(2,3-DIHYDROXYBENZALIDENE)-AM
Abstract

Download : SOLVENT AND PH EFFEC.ppt( 14 )







To investigate the solvent effect, we measured the absorption spectra using the mixture of DMSO and ethanol. Also, the excitation spectra of DMSO-deionized water. The larger the ratio of DMSO, the greater the absorbance and the intensity. At various pH, the absorption and fluorescence spectra were measured and it was concluded that the results at pH 9.45 was the best. Therefore, the effect of several tripositive cation was conducted at pH 9.45. As anticipated, the spectra were shown to become very different when the metal ions(Al3+, Cr3+, Fe3+) were mixed to the ligand solution (solvent), ethanol: H2O= 4:1). 
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